Snell's Law relates the indices of refraction n of the two media to the directions of propagation in terms of the angles to the normal. Snell's law can be derived from Fermat's Principle or from the Fresnel Equations. If the incident medium has the larger index of refraction, then the angle with the normal is increased by refraction. The larger index medium is commonly called the "internal" medium, since air with n=1 is usually the surrounding or "external" medium. You can calculate the condition for total internal reflection by setting the refracted angle = 90° and calculating the incident angle. Since you can't refract the light by more than 90°, all of it will reflect for angles of incidence greater than the angle which gives refraction at 90°.
Optics for Optometry